Preparation of LaB 6 nanoparticles as a novel and effective near-infrared photothermal conversion material

• Published in: Chemical engineering journal (Lausanne, Switzerland : 1996) Vol. 180; pp. 337 - 342
• Main Authors: Chen, Cheng-Jia, Chen, Dong-Hwang
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.01.2012
• Subjects: Bead milling; Lanthanum hexaboride; Nanoparticles; Near infrared; Photothermal conversion; Nanoparticles; Bead milling; Lanthanum hexaboride; Near infrared; Photothermal conversion
• ISSN: 1385-8947; 1873-3212
• DOI: 10.1016/j.cej.2011.11.035

The LaB 6 nanoparticles prepared by bead milling exhibit excellent photothermal conversion property under near infrared irradiation. [Display omitted] ► LaB 6 nanoparticles were prepared by a stirred bead milling process. ► Size reduction induced their near IR absorption and photothermal conversion property. ► Their near IR photothermal conversion property was better than Au nanoshells. ► They could be used as a novel and effective NIR photothermal conversion material. LaB 6 nanoparticles have been prepared successfully by a stirred bead milling process. The anionic surfactant dodecylbenzenesulfonic acid was found to be suitable for the grinding and dispersion of LaB 6 powders, but cationic surfactant polyethyleneimine and nonionic surfactant polyethylene glycol could not yield a stable dispersion. Three kinds of grinding beads with the diameters of 50, 100, and 200 μm all could reduce the mean hydrodynamic diameter of LaB 6 powders to about 100 nm. However, although the grinding rate was slower, using the smaller grinding beads with a diameter of 50 μm could yield a dispersion of LaB 6 nanoparticles with more uniform size. The resulting LaB 6 nanoparticles were confirmed to remain a cubic structure and the contaminant from ZrO 2 beads was below 5 wt%. Furthermore, the LaB 6 nanoparticles exhibited a characteristic absorption around 1000 nm and possessed an excellent near infrared (NIR) photothermal conversion property better than Au nanoshells. Because they were relatively cheap and easy-to-preparation than Au nanorods or nanoshells, the LaB 6 nanoparticles could be used as a novel and effective NIR photothermal conversion material and might find great potential in the biomedical application.