A Flexible Ammonia Gas Sensor Based on a Grafted Polyaniline Grown on a Polyethylene Terephthalate Film

• Published in: Sensors (Basel, Switzerland) Vol. 24; no. 11; p. 3695
• Main Authors: Matsuguchi, Masanobu, Horio, Kaito, Uchida, Atsuya, Kakunaka, Rui, Shiba, Shunsuke
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 06.06.2024; MDPI
• Subjects: Ammonia; Contact angle; Dopamine; Electrodes; flexible sensor; graft polymerization; Hydrochloric acid; NH3 gas sensor; Plastics; polyaniline (PANI); Polyethylene terephthalate; Polymerization; Polymers; room temperature operation; Semiconductors; Sensors; Sulfuric acid; Thin films; Japan; NH3 gas sensor; room temperature operation; flexible sensor; polyaniline (PANI); graft polymerization
• ISSN: 1424-8220; 1424-8220
• DOI: 10.3390/s24113695

A novel NH gas sensor is introduced, employing polyaniline (PANI) with a unique structure called a graft film. The preparation method was simple: polydopamine (PD) was coated on a flexible polyethylene terephthalate (PET) film and PANI graft chains were grown on its surface. This distinctive three-layer sensor showed a response value of 12 for 50 ppm NH in a dry atmosphere at 50 °C. This value surpasses those of previously reported sensors using structurally controlled PANI films. Additionally, it is on par with sensors that combine PANI with metal oxide semiconductors or carbon materials, the high sensitivity of which have been reported. To confirm our film's potential as a flexible sensor, the effect of bending on the its characteristics was investigated. This revealed that although bending decreased the response value, it had no effect on the response time or recovery. This indicated that the sensor film itself was not broken by bending and had sufficient mechanical strength.