Modeling the removal of methylene blue dye using a graphene oxide/TiO2/SiO2 nanocomposite under sunlight irradiation by intelligent system

• Published in: Open Chemistry Vol. 19; no. 1; pp. 157 - 173
• Main Authors: Ahmad, Hanan Haj, Alahmad, Waed
• Format: Journal Article
• Language: English
• Published: De Gruyter 01.01.2021
• Subjects: fractional factorial design; Langmuir; photocatalysis; response surface methodology; sunlight
• ISSN: 2391-5420
• DOI: 10.1515/chem-2021-0025

In this study, a model to improve the degradability of methylene blue (MB) dye using graphene oxide/TiO /SiO nanocomposite under sunlight irradiation is investigated. The effect of operative parameters comprising catalyst concentration, initial dye concentration, and pH on the photocatalytic batch during removal of MB is studied. Fractional factorial design (FFD) and response surface methodology (RSM) are used to design the experiment layout. Graphene oxide (GO)/TiO /SiO nanoparticles are synthesized through sonication and sol–gel methodologies. In the experiments, three levels of catalyst varied in the percentage of TiO pointed as (I) TiO :GO (100%), (II) TiO :GO:SiO (50%), and (III) TiO :GO:SiO (25%) are used. The irradiation interval was 7 h at solar radiation energy 6.35–5.00 kW h/m /day. In the experiments, three levels of catalyst varied in the percentage of TiO pointed as (I) TiO :GO (100%), (II) TiO :GO:SiO (50%), and (III) TiO :GO:SiO (25%) are used. The synthesized catalysts are characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscope, and X-ray photoelectron spectroscopy. ANOVA under 2 FFD is conducted to evaluate the effect of independent factors depending on the value of F as pH of solution, weight of catalyst, and concentration of MB. The adsorption kinetics, experimental design with FFD, and RSM are investigated in this study. The Surface Adsorption kinetics were statistically analyzed, the model that best described the results of each experiment was determined out of the two evaluated kinetics (pseudo-first order, pseudo-second order), for the three photocatalyst composites I, II, and III with the parameters; weight of the catalyst, pH, and initial MB concentration, also percentage degradation is evaluated. RSM results are consistent with the kinetic model; first, the pH is considered as the most significant parameter affecting the removal of the organic pollutant, and second, catalyst II gives the highest percentage removal efficiency of MB. FFD results are consistent with both models where the effect of the independent factor depending on the value of F was pH of solution > weight of catalyst > initial concentration of MB. The percentage removal was in the range from 30 to 99%.