Hochleitnerite, [K(H2O)]Mn2(Ti2Fe)(PO4)4O2(H2O)10 ⋅ 4H2O, a new paulkerrite-group mineral, from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria, Germany

• Published in: European journal of mineralogy (Stuttgart) Vol. 35; no. 4; pp. 635 - 643
• Main Authors: Grey, Ian E, Keck, Erich, Kampf, Anthony R, MacRae, Colin M, Gable, Robert W, Mumme, William G, Wilson, Nicholas C, Glenn, Alexander M, Davidson, Cameron
• Format: Journal Article
• Language: English
• Published: Göttingen Copernicus GmbH 07.08.2023; Copernicus Publications
• Subjects: Cations; Crystal structure; Crystals; Fluorapatite; Iron; Manganese; Mathematical analysis; Mineralogy; Minerals; Pegmatite; Single crystals; Tetrahedra; Titanium; Trimers; Unit cell; White light; Bavaria Germany; Germany
• ISSN: 0935-1221; 1617-4011
• DOI: 10.5194/ejm-35-635-2023

Hochleitnerite, [K(H2O)]Mn2(Ti2Fe)(PO4)4O2(H2O)10 ⋅ 4H2O, is a new paulkerrite-group mineral from the Hagendorf-Süd pegmatite, Oberpfalz, Bavaria, Germany. It was found in specimens of altered zwieselite, in association with fluorapatite, rockbridgeite, columbite and sub-micrometre rods of uranophane. Hochleitnerite occurs as isolated and intergrown pale-yellow, diamond-shaped tablets with thicknesses reaching 50 µm and lengths of 120 µm. The crystals are flattened on {010}, slightly elongated on [001], and bounded by the {111} and {010} forms. The calculated density is 2.40 g cm-3. Optically, hochleitnerite crystals are biaxial (+), with α= 1.615(2), β= 1.621(2) and γ= 1.645(2) (measured in white light). The calculated 2V is 53.8∘. The empirical formula is [K(H2O)](Mn1.512+Fe0.492+)Σ2.00(Ti1.624+Fe0.193+Al0.15)Σ2.96(PO4)4.00[O1.50F0.23(OH)0.27]Σ2.00(H2O)10 ⋅ 4H2O. Hochleitnerite has space group Pbca and unit-cell parameters a= 10.5513(3) Å, b= 20.6855(17) Å,c= 12.4575(4) Å, V= 2718.96(15) Å3 and Z= 4. The crystal structure was refined using single-crystal data to wRobs= 0.082 for 2242 reflections with I > 3σ(I). The crystal structure contains corner-connected linear trimers of Ti-centred octahedra that share corners with PO4 tetrahedra to form 10-member rings parallel to (010). K+ cations and water molecules are located within the rings. Additional corner sharing of the PO4 tetrahedra with MnO2(H2O)4 octahedra occurs along [010] to complete the 3D framework structure.