Enhanced Photostability and Photoluminescence of PbI2 via Constructing Type‐I Heterostructure with ZnO

• Published in: Advanced photonics research Vol. 2; no. 5
• Main Authors: Li, Jixiu, Li, Yuanzheng, Liu, Weizhen, Feng, Qiushi, Huang, Rui, Zhu, Xiaonan, Liu, Xiuling, Zhang, Cen, Xu, Haiyang, Liu, Yichun
• Format: Journal Article
• Language: English
• Published: Hoboken John Wiley & Sons, Inc 01.05.2021; Wiley-VCH
• Subjects: Efficiency; Graphene; Heat conductivity; heterostructures; Lasers; Nanowires; PbI2; photoluminescences; photostability; Polymers; Quantum dots; Radiation; Spectrum analysis; ZnO
• ISSN: 2699-9293; 2699-9293
• DOI: 10.1002/adpr.202000183

Improving the stability of lead iodide (PbI2), especially photostability, is in crucial demand for the realization of application‐level optoelectronic devices. In this regard, deposition of organic polymers on PbI2 as a protective layer is a common strategy to improve its stability, but polymers with low thermal conductivity generally cannot produce the desired effect. Herein, a novel strategy is proposed for improving the photostability of PbI2 at different excitation wavelengths, including 320, 405, and 532 nm, via constructing type‐I heterostructure with ZnO with high thermal conductivity. In addition, due to the type‐I band alignment between PbI2 and ZnO, the photogenerated carriers in ZnO can be transferred to PbI2, resulting in a nearly eightfold photoluminescence enhancement of PbI2 under 320 nm laser excitation. The ZnO as a protective layer forming type‐I heterostructure is evidenced as a feasible strategy for enhancing the photostability and photoluminescence of PbI2, facilitating the development of practical applications. Herein, a novel and feasible strategy is proposed for improving the photostability of lead iodide (PbI2) via constructing type‐I heterostructure with ZnO with high thermal conductivity. In addition, due to the type‐I band alignment between ZnO and PbI2, the photoluminescence intensity of PbI2 is enhanced to nearly eightfold under 320 nm laser excitation.