Fluorescence Intensity Ratio‐based temperature sensor with single Nd3 + :Y2O3 nanoparticles: Experiment and theoretical modeling

• Published in: Nano select Vol. 2; no. 2; pp. 346 - 356
• Main Authors: Galvão, Rodrigo, Santos, Luiz F. dos, Gonçalves, Rogéria R., Menezes, Leonardo de S.
• Format: Journal Article
• Language: English
• Published: Weinheim John Wiley & Sons, Inc 01.02.2021; Wiley-VCH
• Subjects: Continuous radiation; Energy; Lasers; Light; Nanoparticles; nanothermometry; neodymium; Scanning electron microscopy; single nanoparticles; Spectrum analysis; Temperature; Temperature sensors; Yttrium oxide
• ISSN: 2688-4011; 2688-4011
• DOI: 10.1002/nano.202000148

A thermometer based on single Nd3 + :Y2O3 nanoparticles is reported. The nanothermometer relies on the ratio of thermally coupled Nd3 + emission lines accessible by either continuous‐wave upconversion under 880 nm or downconversion under 532 nm excitation wavelengths. Both processes are modeled through rate equation systems based on multiphonon interactions between excited luminescent states, which led to excellent agreement with the experimental data. Moreover, the Y2O3 effective phonon mode energy was determined, showing the appropriateness of the theoretical approach used. The system presented a relative sensitivity up to 1.36% at 300 K while working within the first biological window, thus particularly useful for biological sensing applications. A thermometer based on single Nd3 + :Y2O3 nanoparticles is reported. It relies on the ratio of thermally coupled Nd3 + emission lines accessible by continuous‐wave upconversion under 880 nm or downconversion under 532 nm. The rate equation analysis lead to results that nicely agree with the experimental data. The system showed a relative sensitivity up to 1.36% at 300 K.