3-Benzyl-7-methyl-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexahydro-1H-pyrrolo[3,4-b]quinoline

In the title compound, C32H32N2O2S, the pyrrolidine ring adopts a twist conformation while the tetrahydropyridine ring is in a distorted half-chair conformation. The two rings are trans-fused. The dihedral angle between the sulfonyl and benzyl phenyl rings is 72.54 (14)°. The mole...

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Published inActa crystallographica. Section E, Structure reports online Vol. 65; no. 11; pp. o2924 - o2925
Main Authors K. Chinnakali, D. Sudha, M. Jayagobi, R. Raghunathan, Hoong-Kun Fun
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 01.11.2009
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Summary:In the title compound, C32H32N2O2S, the pyrrolidine ring adopts a twist conformation while the tetrahydropyridine ring is in a distorted half-chair conformation. The two rings are trans-fused. The dihedral angle between the sulfonyl and benzyl phenyl rings is 72.54 (14)°. The molecular structure is stabilized by C—H...O hydrogen bonds, and N—H...π interactions involving the benzyl phenyl ring. The screw-related molecules are linked into chains along the b axis by C—H...O hydrogen bonds and C—H...π interactions. Adjacent inversion-related chains interact via C—H...π interactions, forming a two-dimensional network parallel to the bc plane.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809044481