2,3-Dimethyl-1H-imidazol-3-ium benzenesulfonate–1,2-dimethyl-1H-imidazole co-crystal
In the title co-crystal, C5H9N2+·C6H5O3S−·C5H8N2, the two 1,2-dimethylimidazole rings exist as partially protonated moieties in the asymmetric unit as a two-part disordered unit wherein the acidic hydrogen atom is bound to each ring. The two imidazolium cations share a strong hydrogen bond via the a...
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Published in | IUCrData Vol. 5; no. 5; p. x200689 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
International Union of Crystallography
27.05.2020
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Subjects | |
Online Access | Get full text |
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Summary: | In the title co-crystal, C5H9N2+·C6H5O3S−·C5H8N2, the two 1,2-dimethylimidazole rings exist as partially protonated moieties in the asymmetric unit as a two-part disordered unit wherein the acidic hydrogen atom is bound to each ring. The two imidazolium cations share a strong hydrogen bond via the acidic hydrogen atom, which is disordered between two positions, being bonded to the first versus second imidazole ring in a 0.33 (2) to 0.67 (2) ratio. A benzene sulfonate anion is present for charge balance and interacts with the aromatic H atoms on both imidazole rings as well as with the methyl groups on the rings. |
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ISSN: | 2414-3146 2414-3146 |
DOI: | 10.1107/S2414314620006896 |