catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ2 N:N′] bis(perchlorate) 4,4′-bipyridine disolvate dihydrate]
In the title compound, {[Co(C 10 H 8 N 2 )(H 2 O) 4 ](ClO 4 ) 2 ·2C 10 H 8 N 2 ·2H 2 O} n , slightly distorted octahedrally coordinated Co II ions situated on inversion centers are linked into polycationic chains through 4,4′-bipyridine tethering ligands. These are connected into supramolecular la...
Saved in:
| Published in | Acta crystallographica. Section E, Structure reports online Vol. 64; no. Pt 11; p. m1485 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
International Union of Crystallography
01.11.2008
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Summary: | In the title compound, {[Co(C
10
H
8
N
2
)(H
2
O)
4
](ClO
4
)
2
·2C
10
H
8
N
2
·2H
2
O}
n
, slightly distorted octahedrally coordinated Co
II
ions situated on inversion centers are linked into polycationic chains through 4,4′-bipyridine tethering ligands. These are connected into supramolecular layers by hydrogen bonding involving aqua ligands, perchlorate anions and uncoordinated water molecules. A twofold interpenetrated primitive cubic supramolecular network is formed by the interaction of pseudo-layers by hydrogen bonding between aqua ligands and unligated 4,4′-bipyridine molecules. |
|---|---|
| ISSN: | 1600-5368 1600-5368 |
| DOI: | 10.1107/S1600536808035125 |