SO 2 and SO 3 reactions with [(C 5 Me 5 ) 2 Sm-O-Sm(C 5 Me 5 ) 2 ]: a DFT investigation and comparison with CO 2 reactivity
Recently, it was shown that samarocene oxide [Cp* Sm-O-SmCp* ] with Cp* = C Me could react with organic and inorganic anhydrides. The reactions of [Cp* Sm-O-SmCp* ] with SO and SO are reported using DFT calculations and compared with the reactivity of CO . These reactions exhibit similar features yi...
Saved in:
| Published in | Dalton transactions : an international journal of inorganic chemistry Vol. 46; no. 24; pp. 7660 - 7663 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
England
28.06.2017
|
| Online Access | Get full text |
Cover
Loading…
| Summary: | Recently, it was shown that samarocene oxide [Cp*
Sm-O-SmCp*
] with Cp* = C
Me
could react with organic and inorganic anhydrides. The reactions of [Cp*
Sm-O-SmCp*
] with SO
and SO
are reported using DFT calculations and compared with the reactivity of CO
. These reactions exhibit similar features yielding [Cp*
-Sm-(μ-η
:η
-OSO
)-SmCp*
] similar to [Cp*
-Sm-(μ-η
:η
-OCO
)-SmCp*
] and [Cp*
-Sm-(μ-η
:η
-O
SO
)-SmCp*
] complexes. |
|---|---|
| ISSN: | 1477-9226 1477-9234 |
| DOI: | 10.1039/C7DT01703K |