Cu 3 L 2 metal-organic cages for A 3 -coupling reactions: reversible coordination interaction triggered homogeneous catalysis and heterogeneous recovery

The reported Cu(ii) metal-organic cage (Cu3L2, 1) can be a highly active reusable catalyst to homogeneously catalyze the A3-coupling reaction in CHCl3 and can be heterogeneously recovered by simply adding 1,4-dioxane via formation of the insoluble metal-organic framework (Cu3L2(1,4-dioxane)1.5, 2).

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 54; no. 82; pp. 11550 - 11553
Main Authors Chen, Gong-Jun, Chen, Chao-Qun, Li, Xue-Tian, Ma, Hui-Chao, Dong, Yu-Bin
Format Journal Article
LanguageEnglish
Published England 11.10.2018
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Summary:The reported Cu(ii) metal-organic cage (Cu3L2, 1) can be a highly active reusable catalyst to homogeneously catalyze the A3-coupling reaction in CHCl3 and can be heterogeneously recovered by simply adding 1,4-dioxane via formation of the insoluble metal-organic framework (Cu3L2(1,4-dioxane)1.5, 2).
ISSN:1359-7345
1364-548X
DOI:10.1039/C8CC07208F