Two dominant self-assembly pathways to a Pd 3 L 6 double-walled triangle
An NMR-based quantitative analysis of self-assembly process (QASAP) for the self-assembly of a Pd3L6 double-walled triangle (DWT) from PdPy*4(BF4)2 (Py* indicates 3-chloropyridine) and V-shaped ditopic ligands (L) revealed that DWT was assembled through trinuclear single-walled chains, in which the...
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Published in | Chemical communications (Cambridge, England) Vol. 54; no. 56; pp. 7758 - 7761 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
England
21.05.2018
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Online Access | Get full text |
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Summary: | An NMR-based quantitative analysis of self-assembly process (QASAP) for the self-assembly of a Pd3L6 double-walled triangle (DWT) from PdPy*4(BF4)2 (Py* indicates 3-chloropyridine) and V-shaped ditopic ligands (L) revealed that DWT was assembled through trinuclear single-walled chains, in which the intramolecular macrocyclization and the formation of double-walls took place leading to the final assembly. |
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ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/C8CC02608D |