Two dominant self-assembly pathways to a Pd 3 L 6 double-walled triangle

An NMR-based quantitative analysis of self-assembly process (QASAP) for the self-assembly of a Pd3L6 double-walled triangle (DWT) from PdPy*4(BF4)2 (Py* indicates 3-chloropyridine) and V-shaped ditopic ligands (L) revealed that DWT was assembled through trinuclear single-walled chains, in which the...

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Published inChemical communications (Cambridge, England) Vol. 54; no. 56; pp. 7758 - 7761
Main Authors Tateishi, Tomoki, Kai, Shumpei, Sasaki, Yuya, Kojima, Tatsuo, Takahashi, Satoshi, Hiraoka, Shuichi
Format Journal Article
LanguageEnglish
Published England 21.05.2018
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Summary:An NMR-based quantitative analysis of self-assembly process (QASAP) for the self-assembly of a Pd3L6 double-walled triangle (DWT) from PdPy*4(BF4)2 (Py* indicates 3-chloropyridine) and V-shaped ditopic ligands (L) revealed that DWT was assembled through trinuclear single-walled chains, in which the intramolecular macrocyclization and the formation of double-walls took place leading to the final assembly.
ISSN:1359-7345
1364-548X
DOI:10.1039/C8CC02608D