Efficient luminescent properties and cation recognition ability of heavy group 13 element complexes of N 2 O 2 - and N 2 O 4 -type dipyrrins

The first mononuclear 1 : 1 complexes of heavy group 13 elements (Ga and In) and N2O2/N2O4-type dipyrrins were synthesized and characterized. The N2O2-type complexes showed efficient luminescent properties even in polar solvents. The N2O4-type complexes exhibited fluorometric responses to alkaline e...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 48; no. 35; pp. 13169 - 13175
Main Authors Sumiyoshi, Akinobu, Chiba, Yusuke, Matsuoka, Ryota, Noda, Takumu, Nabeshima, Tatsuya
Format Journal Article
LanguageEnglish
Published England 10.09.2019
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Summary:The first mononuclear 1 : 1 complexes of heavy group 13 elements (Ga and In) and N2O2/N2O4-type dipyrrins were synthesized and characterized. The N2O2-type complexes showed efficient luminescent properties even in polar solvents. The N2O4-type complexes exhibited fluorometric responses to alkaline earth metal ions.
ISSN:1477-9226
1477-9234
DOI:10.1039/C9DT02403D