Photochemical CO 2 reduction with mononuclear and dinuclear rhenium catalysts bearing a pendant anthracene chromophore

A series of anthracene-substituted mononuclear and dinuclear rhenium complexes have been studied for photocatalytic CO2 reduction. The effects on catalytic activity of one versus two covalently-linked active sites, their relative proximity to one another, and the pendant organic chromophore are disc...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 55; no. 7; pp. 993 - 996
Main Authors Liyanage, Nalaka P, Yang, Weiwei, Guertin, Stephen, Sinha Roy, Sayontani, Carpenter, Casey A, Adams, Rebecca E, Schmehl, Russel H, Delcamp, Jared H, Jurss, Jonah W
Format Journal Article
LanguageEnglish
Published England 17.01.2019
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Summary:A series of anthracene-substituted mononuclear and dinuclear rhenium complexes have been studied for photocatalytic CO2 reduction. The effects on catalytic activity of one versus two covalently-linked active sites, their relative proximity to one another, and the pendant organic chromophore are discussed.
ISSN:1359-7345
1364-548X
DOI:10.1039/C8CC09155B