An ultratrace assay of arsenite based on the synergistic quenching effect of Ru(bpy) 3 2+ and arsenite on the electrochemiluminescence of Au-g-C 3 N 4 nanosheets

A novel ratiometric electrochemiluminescence (ECL) indicator has been constructed for ultratrace As(iii) detection based on the synergistic quenching of ECL emission of Au-g-C3N4 NSs using As(iii) and Ru(bpy)32+, meanwhile generating a new ECL signal of Ru(bpy)32+ with an increased intensity. Due to...

Full description

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 54; no. 99; pp. 14001 - 14004
Main Authors Liang, Ru-Ping, Yu, Lu-Dan, Tong, Yuan-Jun, Wen, Shao-Hua, Cao, Shu-Ping, Qiu, Jian-Ding
Format Journal Article
LanguageEnglish
Published England 11.12.2018
Online AccessGet full text

Cover

More Information
Summary:A novel ratiometric electrochemiluminescence (ECL) indicator has been constructed for ultratrace As(iii) detection based on the synergistic quenching of ECL emission of Au-g-C3N4 NSs using As(iii) and Ru(bpy)32+, meanwhile generating a new ECL signal of Ru(bpy)32+ with an increased intensity. Due to the dual quenching effect of As(iii) and Ru(bpy)32+ coupled with the generation of the second ECL signal of Ru(bpy)32+, the sensitivity and selectivity for detecting As(iii) are vastly enhanced.
ISSN:1359-7345
1364-548X
DOI:10.1039/C8CC08353C