Catalytic co-pyrolysis of oil palm empty fruit bunches (EFB) and surgical face mask (SFM) wastes: Thermo-kinetic study, ANN model fitting, and synergistic effect

• Published in: Journal of the Taiwan Institute of Chemical Engineers Vol. 165; p. 105811
• Main Authors: Wee, Melvin Xin Jie, Chin, Bridgid Lai Fui, Saptoro, Agus, Chew, Jiuan Jing, Sunarso, Jaka, Yusup, Suzana, Sharma, Abhishek
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.12.2024
• Subjects: Artificial Neural Network (ANN); Catalytic Co-pyrolysis; DAEM; HZSM-5; Synergistic effect; Thermogravimetric analysis; DAEM; Synergistic effect; Thermogravimetric analysis; HZSM-5; Catalytic Co-pyrolysis; Artificial Neural Network (ANN)
• ISSN: 1876-1070
• DOI: 10.1016/j.jtice.2024.105811

•Thermal degradation of the catalytic pyrolysis of EFB-SFM mixtures was evaluated.•HZSM-5 catalyst showed great affinity towards the sample matrix.•DAEM method used to predict pyrolysis kinetic and thermodynamic parameters.•E and the ΔH parameters showed a reduction of 13.54 % and 14.94 %, respectively.•An ANN model was developed with an accuracy of R2 = 0.9939, and MSE = 1.534 × 10−4. Catalytic co-pyrolysis process is an emerging thermochemical pathway to convert multiple wastes, such as biomass and municipal solid wastes into value added fuels. The ecology would suffer from mishandling of these materials, leading to landfills and microplastic contamination. However, the co-pyrolysis of the surgical face mask (SFM) wastes with biomass remains a niche research area. The co-pyrolysis performance, kinetics and thermodynamics of oil palm empty fruit bunches (EFB) and SFM mixture were evaluated via thermogravimetric analysis (TGA) approach at heating rates from 10 to 100 °C.min−1 with weight ratio of 1:1, 4:1 and 1:4. Additionally, the development of the artificial neural network (ANN) model to represent the thermal degradation behaviour of the overall catalytic co-pyrolysis process for EFB and SFM mixtures. The highest average pyrolysis performance index, Ir value of 8.11 was found in the reaction at 50 °C.min−1. The weight change, ΔWTGA showed the thermal degradation behaviour of EFB and SFM co-pyrolysis exhibited predominantly inhibitory characteristics, as the experimental values were higher than the theoretical values. Moreover, the HZSM-5 catalyst showed great affinity towards the sample matrix, achieving high reduction of activation energy and difference in enthalpy of 13.54 % and 14.94 %, respectively. [Display omitted]