Low temperature-synthesized MgAl 2 O 4 :Eu 3+ nanophosphors and their structural validations using density functional theory: photoluminescence, photocatalytic, and electrochemical properties for multifunctional applications

• Published in: Luminescence (Chichester, England) Vol. 38; no. 7; pp. 1149 - 1166
• Main Authors: S N, Manjula, M, Chandrasekhar, Naik, Ramachandra, V, Revathi, H, Nagabhushana, C R, Ravikumar, B S, Surendra, A, Naveen Kumar
• Format: Journal Article
• Language: English
• Published: England 01.07.2023
• Subjects: photoluminescence; solution combustion synthesis; nanophosphors; Judd-Ofelt parameter; photocatalysis; MgAl2O4:Eu3; electrochemical performance
• ISSN: 1522-7235; 1522-7243
• DOI: 10.1002/bio.4246

A low temperature-assisted and oxalyl dihydrazide fuel-induced combustion synthesized series of uncalcined MgAl O :Eu nanophosphors showed an average crystallite size of ~20 nm, and bandgap energy (E ) of 4.50-5.15 eV, and were validated using density functional theory and found to match closely with the experimental values. The photoluminescence characteristic emission peaks of Eu ions were recorded between 480 and 680 nm. The nanophosphors excited at 392 nm showed f-f transitions assigned as D → F (J = 0, 1, 2, and 3). The optimized MgAl O phosphors had Commission Internationale de l'Eclairage coordinates in the red region, a correlated colour temperature of 2060 K, and a colour purity of 98.83%. The estimated luminescence quantum efficiency ( ) was observed to be ~63% using Judd-Ofelt analysis. Electrochemical and photocatalytic performance were explored and indicated its multifunctional applications. Therefore, MgAl O :Eu nanophosphors could be used for the fabrication of light-emitting diodes, industrial dye degradation, and as electrodes for supercapacitor applications.