Enhancement of near-infrared up-conversion and blue down-conversion luminescence in LuNbO 4 :Yb 3+ ,Tm 3+ with Ga 3+ and Ta 5+ substitutions

• Published in: Luminescence (Chichester, England) Vol. 34; no. 5; pp. 500 - 507
• Main Authors: Im, Min Hyuk, Kim, Young Jin
• Format: Journal Article
• Language: English
• Published: England 01.08.2019
• Subjects: Color; Energy Transfer - radiation effects; Gallium - chemistry; Infrared Rays; Luminescence; Tantalum - chemistry; Thulium - chemistry; Yttrium - chemistry; down-conversion; near infrared; luminescence; LuNbO4; up-conversion
• ISSN: 1522-7235; 1522-7243
• DOI: 10.1002/bio.3625

Under a 980-nm excitation, the up-conversion (UC) spectra of LuNbO :Yb ,Tm powders exhibited predominantly near-infrared bands (~805 nm) of Tm through an energy transfer process from Yb to Tm . Regarding the down-conversion (DC) luminescence of the powders, the photoluminescence excitation spectra consisted of a broad charge transfer band (270 nm) due to [NbO ] and sharp band (360 nm) of Tm , while the corresponding emission spectra exhibited a blue emission at 458 nm. Upon substitution of Ga and Ta for Lu and Nb , respectively, both UC and DC luminescence properties were significantly enhanced. For the Ga substitution, the increased emission intensity could be explained by the crystal field asymmetry surrounding the Tm ions induced by the large difference in ionic radius between Ga and Lu . For the Ta substitution, we believe that an M'-LuTaO substructure was formed in the host, which led to the formation of a TaO octahedral coordination instead of a NbO tetrahedral coordination. Consequently, the crystal symmetry of the local structure was modified, and thus the UC and DC luminescence properties were enhanced. The dual-mode (UC and DC) luminescence demonstrates that LuNbO :Yb ,Tm has a great potential in the fields of temperature sensing probes, anti-counterfeiting, and bioapplications.