Dibromotetra-μ 3 -methoxo-di-μ 2 -methoxo-hexakis(tetrahydrofuran- d 8 )tetramagnesium

The crystal structure of the title compound, [Mg 4 Br 2 (CH 3 O) 6 (C 4 D 8 O) 6 ], consists of discrete molecules with imposed symmetry C i . The tetranuclear compound exhibits two crystallographically independent Mg atoms having distorted octahedral and trigonal–bipyramidal coordination spheres. T...

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Bibliographic Details
Published inActa crystallographica. Section C, Crystal structure communications Vol. 60; no. 10; pp. m482 - m483
Main Authors Walfort, Bernhard, Yousef, Rushdi I., Rüffer, Tobias, Steinborn, Dirk
Format Journal Article
LanguageEnglish
Published 01.10.2004
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Summary:The crystal structure of the title compound, [Mg 4 Br 2 (CH 3 O) 6 (C 4 D 8 O) 6 ], consists of discrete molecules with imposed symmetry C i . The tetranuclear compound exhibits two crystallographically independent Mg atoms having distorted octahedral and trigonal–bipyramidal coordination spheres. The Mg atoms are bridged by two μ 3 -OMe and four μ 2 -OMe ligands, and their coordination is completed by two terminal Br and six tetrahydrofuran ligands.
ISSN:0108-2701
DOI:10.1107/S010827010401933X