Investigation of high-temperature phase transformation in one-dimensional Ta 2 O 5 nanorods

• Published in: Journal of applied crystallography Vol. 43; no. 5; pp. 1062 - 1067
• Main Authors: Devan, Rupesh S., Lin, Jin-Han, Ho, Wei-Der, Wu, Sheng Yun, Liou, Yung, Ma, Yuan-Ron
• Format: Journal Article
• Language: English
• Published: 01.10.2010
• ISSN: 0021-8898
• DOI: 10.1107/S0021889810026646

The thermochromic phase transformations that occur in one-dimensional Ta 2 O 5 nanorods were analysed at elevated temperatures ranging from 300 to 750 K. X-ray photoemission spectroscopy data revealed not only the electronic structures and chemical properties of the one-dimensional Ta 2 O 5 nanorods, but also their stoichiometric Ta and O compositions. High-temperature X-ray diffraction data revealed complex and polymorphic thermochromic phase transformations of the α(1 0 11), α(200), α(2 0 10), β(3 11 1) and β(2 21 1) lattice planes in the one-dimensional Ta 2 O 5 nanorods, which incorporate β to α (β–α), β to β (β–β), α to α (α–α) and α to β (α–β) phase transitions. The thermochromic phase transformations between α- and β-phase crystals can be explained by a shift in 2θ and expansion of the d spacing of the lattice planes.