Oxidative Stability and Volatile Formations in Linoleic Acid‐D 2 O Models in the Presence of Deuteron or Electron Donors

• Published in: Journal of the American Oil Chemists' Society Vol. 94; no. 11; pp. 1385 - 1392
• Main Authors: Oh, Sumi, Lee, Chankyu, Kim, SungHwa, Choi, HyungSeok, Kim, Mi‐Ja, Lee, JaeHwan
• Format: Journal Article
• Language: English
• Published: 01.11.2017
• ISSN: 0003-021X; 1558-9331
• DOI: 10.1007/s11746-017-3044-5

Abstract Effects of deuteron (D + ) and electron donors on the oxidative stability in linoleic acid–water model systems were evaluated by analyzing headspace oxygen content and headspace volatiles. Acetic acid‐ d and tetrakis(dimethylamino)ethylene (TDAE) were selected as a deuteron and an electron donor, respectively. Samples containing acetic acid‐ d had significantly lower headspace oxygen content than controls while those containing TDAE had significantly higher headspace oxygen content ( p < 0.05). Combination of acetic acid‐ d and TDAE accelerated the consumption of headspace oxygen. Volatiles including t ‐2‐heptenal, 2‐octenal, or 2,4‐octadienal had higher mass to charge ratio ( m / z ) of (molecular weight +1)/molecular weight in samples with deuterium oxide than in samples with deuterium free water. However, no significant difference was observed in the m / z ratio of (molecular weight +1)/molecular weight of those volatiles among samples with or without deuteron or electron donors. Also, lipid hydroperoxides with deuterium, were not found in samples containing deuterium oxide and acetic acid‐ d . Therefore, added acetic acid‐ d may not be involved on the formation of lipid hydroperoxides and volatiles directly.