Tetrahedral Silicon‐Centered Dibenzoylmethanatoboron Difluorides: Synthesis, Crystal Structure, and Photophysical Behavior in Solution and the Solid State

The Cover Feature shows the mechanofluorochromic behavior of an organosilicon derivative of dibenzoylmethanatoboron difluoride (DBMBF2) which has a deep‐yellow fluorescence in the crystal state. The grinding of these crystals leads to the destruction of the ground‐state structures, which are charact...

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Published inChemPlusChem (Weinheim, Germany) Vol. 85; no. 6; p. 1090
Main Authors Kononevich, Yuriy N., Temnikov, Maxim N., Korlyukov, Alexander A., Volodin, Alexander D., Dorovatovskii, Pavel V., Sazhnikov, Viacheslav A., Safonov, Andrey A., Ionov, Dmitriy S., Ivanov, Anatoly A., Surin, Nikolay M., Svidchenko, Evgeniya A., Muzafarov, Aziz M.
Format Journal Article
LanguageEnglish
Published 01.06.2020
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Summary:The Cover Feature shows the mechanofluorochromic behavior of an organosilicon derivative of dibenzoylmethanatoboron difluoride (DBMBF2) which has a deep‐yellow fluorescence in the crystal state. The grinding of these crystals leads to the destruction of the ground‐state structures, which are characterized by the highest degree of overlap of the phenyl rings, and results in blue‐shifted fluorescence. More information can be found in the Full Paper by Yu. Kononevich and co‐workers (DOI: 10.1002/cplu.201900732).
ISSN:2192-6506
2192-6506
DOI:10.1002/cplu.202000241