Li 2 PbF 6 and SrPbF 6 Revisited
Herein we present the crystal structure of lithium hexafluoridoplumbate(IV) determined from powder X‐ray diffraction data. The cell parameters are a = 5.01067(3), c = 4.66340(5) Å, V = 101.3969(13) Å 3 at T = 293 K. Li 2 PbF 6 is isotypic to Li 2 ZrF 6 , space group P 3 1 m (no. 162). The measured R...
Saved in:
| Published in | Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 644; no. 24; pp. 1721 - 1726 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
31.12.2018
|
| Online Access | Get full text |
Cover
Loading…
| Summary: | Herein we present the crystal structure of lithium hexafluoridoplumbate(IV) determined from powder X‐ray diffraction data. The cell parameters are
a
= 5.01067(3),
c
= 4.66340(5) Å,
V
= 101.3969(13) Å
3
at
T
= 293 K. Li
2
PbF
6
is isotypic to Li
2
ZrF
6
, space group
P
3
1
m
(no. 162). The measured Raman spectrum is compared with the quantum chemically calculated spectrum. Furthermore, we determined the decomposition temperature of Li
2
PbF
6
. We also present the corrected space group and crystal structure for SrPbF
6
which was previously reported as
P
4
2
/
mmc
(no. 131) and could now be corrected to space group
P
4
2
/
mcm
[no. 132,
a
= 5.21719(3),
c
= 8.92771(11) Å,
V
= 243.004(4) Å
3
,
T
= 293 K]. |
|---|---|
| ISSN: | 0044-2313 1521-3749 |
| DOI: | 10.1002/zaac.201800299 |