Ceramic Counterflow Reactor for Efficient Conversion of CO 2 to Carbon‐Rich Syngas

Abstract CO 2 is a suitable feedstock for syngas production. Possible co‐reactants to convert CO 2 are hydrogen or methane. Hydrogen can be produced from electrolysis of water with renewable energy, whereby pure oxygen is obtained. Consequently, a simultaneous partial combustion of the energy‐rich c...

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Bibliographic Details
Published inChemie ingenieur technik Vol. 87; no. 6; pp. 726 - 733
Main Authors Kelling, René, Dubbe, Hendrik, Eigenberger, Gerhart, Nieken, Ulrich
Format Journal Article
LanguageEnglish
Published 01.06.2015
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Summary:Abstract CO 2 is a suitable feedstock for syngas production. Possible co‐reactants to convert CO 2 are hydrogen or methane. Hydrogen can be produced from electrolysis of water with renewable energy, whereby pure oxygen is obtained. Consequently, a simultaneous partial combustion of the energy‐rich co‐reactants (H 2 or CH 4 ) with oxygen is possible to compensate for the required heat of reaction and to achieve high temperatures. This is crucial for both, high CO 2 conversion and the prevention of harmful coke formation. For this application a new, scalable reactor concept is proposed. A proof of concept is presented both experimentally and model‐based. The model predicts high CO 2 conversion and syngas production in industrial scale while maintaining defined temperature limits so that coke formation is avoided.
ISSN:0009-286X
1522-2640
DOI:10.1002/cite.201400128