Synthese und Kristallstruktur des Lewis‐Säure/Base‐Addukts AlCl 3 ·C 3 N 3 Cl 3
Abstract Synthesis and Crystal Structure of the Lewis Acid‐Base Adduct AlCl 3 ·C 3 N 3 Cl 3 The reaction between cyanuric chloride (C 3 N 3 Cl 3 ) and the strong Lewis acid AlCl 3 yielded colorless crystals of the adduct AlCl 3 ·C 3 N 3 Cl 3 . The crystal structure was determined by single crystal X...
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| Published in | Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 633; no. 3; pp. 470 - 472 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
01.03.2007
|
| Online Access | Get full text |
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| Summary: | Abstract
Synthesis and Crystal Structure of the Lewis Acid‐Base Adduct AlCl
3
·C
3
N
3
Cl
3
The reaction between cyanuric chloride (C
3
N
3
Cl
3
) and the strong Lewis acid AlCl
3
yielded colorless crystals of the adduct AlCl
3
·C
3
N
3
Cl
3
. The crystal structure was determined by single crystal X‐ray diffraction at room temperature and was solved in the space group
$P{\bar1}$
with Z = 4,
a
= 7.3802(7) Å,
b
= 9.688(1) Å,
c
= 16.272(2) Å, α = 72.80(1)°,
β
= 89.97(1)°,
γ
= 87.23(1)°, and
V
= 1110.0(2) Å
3
. In the crystal structure, AlCl
3
is closely associated to the triazine ring with Al–N distances of 2.042(3) Å and 2.067(4) Å, respectively. The AlCl
3
·C
3
N
3
Cl
3
units are connected with each other via intermolecular N···Cl donor–acceptor interactions, forming tape‐like arrangements in the ac‐plane, with tapes running parallel to the
a
‐axis. |
|---|---|
| ISSN: | 0044-2313 1521-3749 |
| DOI: | 10.1002/zaac.200600316 |