Highly Active Heterogeneous PdCl 2 /MOF Catalyst for Suzuki–Miyaura Cross‐Coupling Reactions of Aryl Chloride

The exploration of highly efficient Pd/MOF heterogeneous catalyst system for the Suzuki–Miyaura cross‐coupling (SMC) reactions of aryl chlorides is still challenging. Herein, a PdCl 2 /UiO‐67‐bpydc was successfully synthesized by immobilizing a low amount of PdCl 2 onto the zirconium‐based MOF (UiO‐...

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Published inZeitschrift für anorganische und allgemeine Chemie (1950) Vol. 646; no. 15; pp. 1336 - 1341
Main Authors Gong, Xue‐Fang, Zhang, Ling‐Yan, Zhang, Hui‐Xin, Cui, Yu‐Meng, Jin, Fen‐Chun, Liu, Yu, Zhai, Yu‐Feng, Li, Jin‐Heng, Liu, Gui‐Yan, Zeng, Yong‐Fei
Format Journal Article
LanguageEnglish
Published 14.08.2020
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Summary:The exploration of highly efficient Pd/MOF heterogeneous catalyst system for the Suzuki–Miyaura cross‐coupling (SMC) reactions of aryl chlorides is still challenging. Herein, a PdCl 2 /UiO‐67‐bpydc was successfully synthesized by immobilizing a low amount of PdCl 2 onto the zirconium‐based MOF (UiO‐67‐bpydc). PdCl 2 /UiO‐67‐bpydc showed excellent catalytic performance and good recycle ability for the SMC reaction of aryl chlorides under an ambient condition. Furthermore, PdCl 2 /UiO‐67‐bpydc retains the high catalytic activity even after five cycles, and exhibited excellent substrate size selectivity.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.202000132