Tin‐Mediated Route to Polytungstates of Rh II and Pd II
Abstract Three polyoxotungstates of Sn II , Pd II , and Rh II , Na 8 [H 2 SnW 12 O 42 ] · n H 2 O [ 1 , n = 22.75 ( 1a ) and n = 31.10 ( 1b )], Na 2 K(H)[Pd(H 2 O) 4 ][H 2 W 12 O 48 {Pd(H 2 O) 3 } 2 ] · 10H 2 O ( 2 ), and Na 8 [Rh 2 (H 2 O) 2 (W 5 O 18 ) 2 ] · 21.25H 2 O ( 3 ) were obtained. The com...
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| Published in | European journal of inorganic chemistry Vol. 2013; no. 10-11; pp. 1772 - 1779 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
01.04.2013
|
| Online Access | Get full text |
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| Summary: | Abstract
Three polyoxotungstates of Sn
II
, Pd
II
, and Rh
II
, Na
8
[H
2
SnW
12
O
42
]
·
n
H
2
O [
1
,
n
= 22.75 (
1a
) and
n
= 31.10 (
1b
)], Na
2
K(H)[Pd(H
2
O)
4
][H
2
W
12
O
48
{Pd(H
2
O)
3
}
2
]
·
10H
2
O (
2
), and Na
8
[Rh
2
(H
2
O)
2
(W
5
O
18
)
2
]
·
21.25H
2
O (
3
) were obtained. The complexes were characterized by X‐ray analysis, solid‐state
1
H NMR spectroscopy, IR spectroscopy, thermogravimetric analysis, and elemental analysis. |
|---|---|
| ISSN: | 1434-1948 1099-0682 |
| DOI: | 10.1002/ejic.201201162 |