Electrosynthesis of Arylsulfonamides from Amines and Sodium Sulfinates Using H 2 O‐NaI as the Electrolyte Solution at Room Temperature

Abstract With H 2 O as the solvent and NaI as the supporting electrolyte, a green and efficient electrochemical route has been developed to synthesize arylsulfonamides via I 2 electrogenerated in situ at a graphite anode to promote the reaction of sodium sulfinates with aromatic or aliphatic primary...

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Bibliographic Details
Published inChinese journal of chemistry Vol. 34; no. 12; pp. 1277 - 1282
Main Authors Zhang, Chen, Chen, Yibin, Yuan, Gaoqing
Format Journal Article
LanguageEnglish
Published 01.12.2016
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Summary:Abstract With H 2 O as the solvent and NaI as the supporting electrolyte, a green and efficient electrochemical route has been developed to synthesize arylsulfonamides via I 2 electrogenerated in situ at a graphite anode to promote the reaction of sodium sulfinates with aromatic or aliphatic primary and secondary amines. The target products could be obtained in good to excellent yields at room temperature.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201600452