Untersuchungen an Polyhalogeniden, XXXVII [1]. Heptaiodide(3-) von Amminkomplexen des Chroms und Cobalts: Hexamminchrom(III)heptaiodid [Cr(NH 3 ) 6 ](I 3 )(I 4 ) und die Tri-μ-hydroxo-bis[metall(III)-triammin]heptaiodide [(NH 3 ) 3 M(OH) 3 M(NH 3 ) 3 ](I 3 ) 2 I mit M = Co, Cr / Studies o f Polyhalides, XXXVII [1]. Heptaiodides(3-) of Ammine Complexes of Chromium and Cobalt: Hexamminechromium(III) heptaiodide [Cr(NH 3 ) 6 ](I 3 )(I 4 ) and the Tri-μ-hydroxo-bis[metal(III)-triammine] heptaiodides
Abstract The new compounds [Cr(NH 3 ) 6 ](I 3 )(I 4 ) and [(NH 3 ) 3 M(OH) 3 M(NH 3 ) 3 ](I 3 ) 2 I with M = Cr, Co have been prepared by the reaction of [M(NH 3 ) 6 ]X 3 (M = Cr, Co; X = Cl, I, NO 3 ), KI, and I 2 in water under controlled stoichiometric and pH conditions. The first compound is iso...
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Published in | Zeitschrift für Naturforschung. B, A journal of chemical sciences Vol. 53; no. 10; pp. 1127 - 1134 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
01.10.1998
|
Online Access | Get full text |
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Summary: | Abstract
The new compounds [Cr(NH
3
)
6
](I
3
)(I
4
) and [(NH
3
)
3
M(OH)
3
M(NH
3
)
3
](I
3
)
2
I with M = Cr, Co have been prepared by the reaction of [M(NH
3
)
6
]X
3
(M = Cr, Co; X = Cl, I, NO
3
), KI, and I
2
in water under controlled stoichiometric and pH conditions. The first compound is isotypic with the cobalt compound of the same composition. It crystallizes in the monoclinic space group I
2
/m with a = 984.7(3), b = 786.6(1), c = 1330.1(3) pm, β = 95.34(2)° and Z = 2 and contains nearly octahedral cations [Cr(NH
3
)
6
]
3+
, a linear triiodide ion I
3
-
and a tetraiodide ion I
42-
. The two other compounds are isotypic. They crystallize in the orthorhombic space group Pnma with a = 2629.6( 14) / 2633.5(2), b = 798.3(11) / 797.3(1), c = 1127.6(7) / 1125.7( 1) pm and Z = 4 for Co / Cr respectively. The heptaiodide(3-) ion is broken into two triiodide ions and one iodide ion |
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ISSN: | 0932-0776 1865-7117 |
DOI: | 10.1515/znb-1998-1008 |