The first two examples of halogen bonding with a sigma hole-donating fluorine in the C sp3 –F⋯O sp3 interaction from polyfluorinated trans -dihalo-palladium( ii ) di-substituted pyridine complexes

The first two examples of halogen bonding in the C sp3 –F⋯O sp3 interaction have been both experimentally and theoretically proved for trans -[PdX 2 (3-HCF 2 CF 2 CH 2 OCH 2 py) 2 ] complexes where X = Cl and Br. Both metal complexes with a C sp3 –F⋯O sp3 halogen bond have a σ hole donating fluorine...

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Published inChemical communications (Cambridge, England) Vol. 55; no. 95; pp. 14259 - 14262
Main Authors Elakkat, Vijayanath, Chang, Chu-Chun, Chen, Jun-Yu, Fang, Yung-Cheng, Shen, Chia-Rui, Liu, Ling-Kung, Lu, Norman
Format Journal Article
LanguageEnglish
Published 26.11.2019
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Summary:The first two examples of halogen bonding in the C sp3 –F⋯O sp3 interaction have been both experimentally and theoretically proved for trans -[PdX 2 (3-HCF 2 CF 2 CH 2 OCH 2 py) 2 ] complexes where X = Cl and Br. Both metal complexes with a C sp3 –F⋯O sp3 halogen bond have a σ hole donating fluorine.
ISSN:1359-7345
1364-548X
DOI:10.1039/C9CC06731K