Crystal growth and characterization of a mixed laser crystal: Nd-doped Gd 0.89 La 0.1 NbO 4

• Published in: RSC advances Vol. 7; no. 57; pp. 35666 - 35671
• Main Authors: Ding, Shoujun, Zhang, Qingli, Liu, Wenpeng, Luo, Jianqiao, Peng, Fang, Wang, Xiaofei, Sun, Guihua, Sun, Dunlu
• Format: Journal Article
• Language: English
• Published: 2017
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/C7RA05380K

Herein, a Nd-doped GdLaNbO 4 (Nd:GLNO) single crystal has been grown successfully using the Czochralski method. The segregation coefficient of Nd 3+ ions in the Nd:GLNO crystal is measured to be 0.71. The X-ray power diffraction patterns of the Nd:GLNO crystal confirm that the as-grown crystal has the same crystal structure as pure GdNbO 4 . The structural parameters of the as-grown crystal are obtained via an X-ray Rietveld refinement method. The absorption spectrum, fluorescence spectrum, and fluorescence decay curve of Nd:GLNO were obtained at room temperature. The small emission cross-section at 1065 nm and long fluorescence lifetime of Nd 3+ ions (176.4 μs) indicate that the Nd:GLNO crystal is suitable for generating an ultrashort pulse laser. A maximum continuous wave (CW) laser output power of 957 mW is achieved at 1.06 μm, corresponding to an optical-to-optical conversion efficiency of 30.3% and slope efficiency of 34.2%. All the obtained results imply that this crystal is a novel mixed niobate-based laser host suitable for laser diode pumps.