Study of an SmBO 3 –ScBO 3 system and new SmSc(BO 3 ) 2 orthoborate

A new SmSc(BO 3 ) 2 compound was discovered from the study of SmBO 3 –ScBO 3 by solid-state synthesis. The obtained compound was grown from a stoichiometric melt by a spontaneous crystallization method, and crystallizes in the space group R 3̄ with the cell parameters of a = 4.8951(6) Å and c = 16.3...

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Published inCrystEngComm Vol. 23; no. 6; pp. 1482 - 1488
Main Authors Kuznetsov, Artem B., Kokh, Konstantin A., Kononova, Nadezda G., Shevchenko, Vyacheslav S., Rashchenko, Ssergey V., Lapin, Ivan N., Svetlichnyi, Valery A., Uralbekov, Bolat, Bolatov, Asset, Simonova, Ekaterina A., Kokh, Alexander E.
Format Journal Article
LanguageEnglish
Published 15.02.2021
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Summary:A new SmSc(BO 3 ) 2 compound was discovered from the study of SmBO 3 –ScBO 3 by solid-state synthesis. The obtained compound was grown from a stoichiometric melt by a spontaneous crystallization method, and crystallizes in the space group R 3̄ with the cell parameters of a = 4.8951(6) Å and c = 16.3012(2) Å. In addition, phase equilibria in this system in the 900–1300 °C temperature range were studied by X-ray diffraction and thermal analyses, as well as special diffusion experiments.
ISSN:1466-8033
1466-8033
DOI:10.1039/D0CE01783C