Organic synthesis of fixed CO 2 using nitrogen as a nucleophilic center

In this review, recent progress in the application of CO 2 as an electrophilic reagent and nitrogen as a nucleophilic center under different catalytic conditions in organic synthesis is summarized. The used catalytic methods in the reactions of CO 2 and nitrogen are classified as metal catalysis, me...

Full description

Saved in:
Bibliographic Details
Published inOrganic & biomolecular chemistry Vol. 18; no. 39; pp. 7774 - 7788
Main Authors Xiong, Ting-Kai, Li, Xue-Jun, Zhang, Min, Liang, Ying
Format Journal Article
LanguageEnglish
Published 14.10.2020
Online AccessGet full text

Cover

More Information
Summary:In this review, recent progress in the application of CO 2 as an electrophilic reagent and nitrogen as a nucleophilic center under different catalytic conditions in organic synthesis is summarized. The used catalytic methods in the reactions of CO 2 and nitrogen are classified as metal catalysis, metal-free catalysis, photocatalysis and electrocatalysis. Various catalytic conditions have been used to solve the problems of thermodynamic properties and stability of CO 2 . The transformation mechanisms of these reactions are discussed.
ISSN:1477-0520
1477-0539
DOI:10.1039/D0OB01590C