Single crystals of undoped Li 2 WO 4 and Li 2 W 1−0.0125 Mo 0.0125 O 4 : formation enthalpies, heat capacity in the temperature range 320–997 K
The Li 2 WO 4 single crystal was first grown by applying the Czochralski technique with weight control and low-temperature-gradients. A single crystal of Li 2 WO 4 is one of the perspective materials for researching rare events. The heat capacity for a Li 2 W 1−0.0125 Mo 0.0125 O 4 single crystal ha...
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Published in | Dalton transactions : an international journal of inorganic chemistry Vol. 50; no. 35; pp. 12130 - 12136 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
14.09.2021
|
Online Access | Get full text |
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Summary: | The Li
2
WO
4
single crystal was first grown by applying the Czochralski technique with weight control and low-temperature-gradients. A single crystal of Li
2
WO
4
is one of the perspective materials for researching rare events. The heat capacity for a Li
2
W
1−0.0125
Mo
0.0125
O
4
single crystal has been determined by DSC calorimetry in the temperature range 320–997 K for the first time. No anomalies in the heat capacity associated with phase transitions were found. The standard formation enthalpy for the Li
2
WO
4
single crystal was studied using reaction calorimetry. It has been shown that the relation of standard formation enthalpies for Li
2
W
1−
x
Mo
x
O
4
(
x
= 0.15–0) with function (1−
x
)W +
x
Mo are close to linear, which allows one to predict the thermodynamic properties for single crystals with isotopes Li
2
W
186
1−0.0125
Mo
100
0.0125
O
4
and Li
2
W
186
O
4
. It was shown that single crystals with isotopes are more thermodynamically stable than without isotopes. |
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ISSN: | 1477-9226 1477-9234 |
DOI: | 10.1039/D1DT01620B |