Pb 3 [C 6 (CH 3 ) 3 (CO 2 ) 3 H 6 ] 2 [DMF] 3 : first layered Pb-Kemp's triacid complex

An unprecedented layered Pb-Kemp's triacid compound, Pb 3 [C 6 (CH 3 ) 3 (CO 2 ) 3 H 6 ] 2 [DMF] 3 , has been synthesized. The material exhibits a selective CO 2 adsorption, a reversible DMF coordination, and an intercalative hexanal addition reaction. A competing crystallization reaction under...

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Published inChemical communications (Cambridge, England) Vol. 51; no. 67; pp. 13166 - 13169
Main Authors Kim, Saet Byeol, Lee, Dong Woo, Chang, Suk-Kyu, Ok, Kang Min
Format Journal Article
LanguageEnglish
Published 2015
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Summary:An unprecedented layered Pb-Kemp's triacid compound, Pb 3 [C 6 (CH 3 ) 3 (CO 2 ) 3 H 6 ] 2 [DMF] 3 , has been synthesized. The material exhibits a selective CO 2 adsorption, a reversible DMF coordination, and an intercalative hexanal addition reaction. A competing crystallization reaction under solvothermal conditions using Pb 2+ and Cd 2+ with Kemp's triacid reveals higher selectivity of Cd 2+ over Pb 2+ .
ISSN:1359-7345
1364-548X
DOI:10.1039/C5CC05360A