Deportment of cobalt bismuth nanoferrites in Kevlar‐supported c ellulose acetate membranes for heavy metal‐salts rejection profile

• Published in: Journal of applied polymer science Vol. 139; no. 40
• Main Authors: Afzal, Amina, Rafique, Muhammad Shahid, Iqbal, Sadia Sagar, Rafique, Muhammad
• Format: Journal Article
• Language: English
• Published: 20.10.2022
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.52962

Abstract The designed novel hybrid laminate membranes have been synthesized with silane surface functionalized Kevlar fabric packed between two layers of cobalt bismuth nanoferrites (CBF)‐loaded cellulose acetate. Primarily, nanoreinforcement; Co‐Bi nano‐ferrites were synthesized using sol–gel technique and functionalization is carried out using 3‐aminpropyl‐tri‐methoxysilane. Secondarily, thermally assisted evaporation methodology coupled with dip‐coating is adopted to synthesize hybrid Kevlar laminate membranes. Finally, structural, thermal, and flux along rejection studies are done on resultant hybrid membranes. The surface morphology, porosity generation, and homogeneous distribution of nanoincorporation with various concentration are revealed from micrographs of SEM of membranes. Noteworthy, impact of nanoreinforcement has been observed to holdup thermal oxidation of synthesized unique formulations of hybrid membranes employing TGA. Presence of CBF in cellulose acetate (CA)/Kevlar laminate membranes are modified glass transition and crystallization temperatures as cleared in DSC. De‐ionized water for flux and heavy metal salts rejection capabilities of each formulated membrane were tested at applied pressures 60, 120, and 180 psi. The important findings are indicated that, increasing concentration of CBF loading in CA remarkably enhanced efficacy of metal‐nitrates rejection with membranes. It is attributed to sole magneto‐physiochemical behavior of nanoferrites that, facilitate enhanced adsorption in designed hybrid membranes for heavy metal rejection from industrial wastes.