Ultrastable Mesostructured Silica Vesicles

• Published in: Science (American Association for the Advancement of Science) Vol. 282; no. 5392; pp. 1302 - 1305
• Main Authors: Kim, Seong Su, Zhang, Wenzhong, Pinnavaia, Thomas J.
• Format: Journal Article
• Language: English
• Published: Washington, DC American Society for the Advancement of Science 13.11.1998; American Association for the Advancement of Science; The American Association for the Advancement of Science
• Subjects: Absorbents; Adsorption; Chemistry; Colloidal state and disperse state; Curves; Ethanol; Exact sciences and technology; General and physical chemistry; Isotherms; Molecules; Porous materials; Roasting; Silicate minerals; Surfactants; Water pressure; Vesicle; Microporosity; Surfactant; Silica; Molecular sieve
• ISSN: 0036-8075; 1095-9203
• DOI: 10.1126/science.282.5392.1302

A family of mesoporous molecular sieves (denoted MSU-G) with vesiclelike hierarchical structures and unprecedented thermal (1000°C) and hydrothermal stabilities (more than 150 hours at 100°C) associated with high SiO$_4$ crosslinking was prepared through a supramolecular assembly pathway that relies on hydrogen bonding between electrically neutral gemini surfactants of the type C$_n$H$_{2n+1}$NH(CH$_2$)$_2$NH$_2$ and silica precursors derived from tetraethylorthosilicate. The vesicle shells are constructed of one or more undulated silica sheets that are about 3 nanometers thick with mesopores (average diameters from 2.7 to 4.0 nanometers) running both parallel and orthogonal to the silica sheets, which makes the framework structure bicontinuous and highly accessible. Catalytic metal ion centers [for example, Ti(IV) and Al(III)] have been incorporated into the framework with the retention of hierarchical structure.