Frequent new particle formation over the high Arctic pack ice by enhanced iodine emissions

• Published in: Nature communications Vol. 11; no. 1; p. 4924
• Main Authors: Baccarini, Andrea, Karlsson, Linn, Dommen, Josef, Duplessis, Patrick, Vüllers, Jutta, Brooks, Ian M., Saiz-Lopez, Alfonso, Salter, Matthew, Tjernström, Michael, Baltensperger, Urs, Zieger, Paul, Schmale, Julia
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 01.10.2020; Nature Publishing Group; Nature Portfolio
• Subjects: 140/58; 704/106/35; 704/106/35/824; Autumn; Clouds; Condensation nuclei; Diameters; Humanities and Social Sciences; Iodine; multidisciplinary; Pack ice; Polar environments; Science; Science (multidisciplinary); Sulfuric acid; Ultrafines; Vapors; Arctic Ocean; Arctic region
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-020-18551-0

In the central Arctic Ocean the formation of clouds and their properties are sensitive to the availability of cloud condensation nuclei (CCN). The vapors responsible for new particle formation (NPF), potentially leading to CCN, have remained unidentified since the first aerosol measurements in 1991. Here, we report that all the observed NPF events from the Arctic Ocean 2018 expedition are driven by iodic acid with little contribution from sulfuric acid. Iodic acid largely explains the growth of ultrafine particles (UFP) in most events. The iodic acid concentration increases significantly from summer towards autumn, possibly linked to the ocean freeze-up and a seasonal rise in ozone. This leads to a one order of magnitude higher UFP concentration in autumn. Measurements of cloud residuals suggest that particles smaller than 30 nm in diameter can activate as CCN. Therefore, iodine NPF has the potential to influence cloud properties over the Arctic Ocean. Which vapors are responsible for new particle formation in the Arctic is largely unknown. Here, the authors show that the formation of new particles at the central Arctic Ocean is mainly driven by iodic acid and that particles smaller than 30 nm in diameter can activate as cloud condensation nuclei.