Visible-Light-Induced Oxidative Decarboxylative Coupling of Phenylacetic Acid Derivatives Using SF 6 as an Oxidant

A visible-light-mediated decarboxylative coupling reaction of phenylacetic acid derivatives, featuring sulfur hexafluoride (SF ) as the oxidant, has been developed. This metal-free method allows for the synthesis of a series of bibenzyl derivatives and complex all-carbon skeletons, facilitating effi...

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Bibliographic Details
Published inOrganic letters Vol. 26; no. 27; pp. 5652 - 5656
Main Authors Zuo, Ya-Wen, Zhao, Yue, Zhang, Yi-Fan, Guo, Xiao-Yu, Wu, Tian-Rui, Jin, Ruo-Xing, Wang, Xi-Sheng
Format Journal Article
LanguageEnglish
Published United States 12.07.2024
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Summary:A visible-light-mediated decarboxylative coupling reaction of phenylacetic acid derivatives, featuring sulfur hexafluoride (SF ) as the oxidant, has been developed. This metal-free method allows for the synthesis of a series of bibenzyl derivatives and complex all-carbon skeletons, facilitating efficient utilization and degradation of the greenhouse gas SF .
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.4c01609