Efficient overall water splitting in acid with anisotropic metal nanosheets

• Published in: Nature communications Vol. 12; no. 1; p. 1145
• Main Authors: Wu, Dongshuang, Kusada, Kohei, Yoshioka, Satoru, Yamamoto, Tomokazu, Toriyama, Takaaki, Matsumura, Syo, Chen, Yanna, Seo, Okkyun, Kim, Jaemyung, Song, Chulho, Hiroi, Satoshi, Sakata, Osami, Ina, Toshiaki, Kawaguchi, Shogo, Kubota, Yoshiki, Kobayashi, Hirokazu, Kitagawa, Hiroshi
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 16.02.2021; Nature Publishing Group; Nature Portfolio
• Subjects: 140/146; 147/137; 639/301/357/354; 639/4077/909; 639/638/77/886; Acids; Atomic beam spectroscopy; Atoms & subatomic particles; Catalysts; Electrolytic cells; Electron microscopy; Humanities and Social Sciences; Hydrogen; Hydrogen production; Metal oxides; Metals; Microscopy; multidisciplinary; Nanomaterials; Nanosheets; Oxygen; Oxygen evolution reactions; Science; Science (multidisciplinary); Sheets; Solid solutions; Spectroscopy; Splitting; Tomography; Water splitting
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-021-20956-4

Water is the only available fossil-free source of hydrogen. Splitting water electrochemically is among the most used techniques, however, it accounts for only 4% of global hydrogen production. One of the reasons is the high cost and low performance of catalysts promoting the oxygen evolution reaction (OER). Here, we report a highly efficient catalyst in acid, that is, solid-solution Ru‒Ir nanosized-coral (RuIr-NC) consisting of 3 nm-thick sheets with only 6 at.% Ir. Among OER catalysts, RuIr-NC shows the highest intrinsic activity and stability. A home-made overall water splitting cell using RuIr-NC as both electrodes can reach 10 mA cm −2 geo at 1.485 V for 120 h without noticeable degradation, which outperforms known cells. Operando spectroscopy and atomic-resolution electron microscopy indicate that the high-performance results from the ability of the preferentially exposed {0001} facets to resist the formation of dissolvable metal oxides and to transform ephemeral Ru into a long-lived catalyst. Ru is one of the most active metals for oxygen evolution reaction, but it quickly dissolves in acidic electrolyte particularly in nanosized form. Here, the authors show that coral-like solid-solution Ru‒Ir consisting of 3 nm-thick sheets with only 6 at% Ir is a long-lived catalyst with high activity.