Selective Hydrogenation of Furfural to Furfuryl Alcohol in the Presence of a Recyclable Cobalt/SBA-15 Catalyst

• Published in: ChemSusChem Vol. 8; no. 11; pp. 1885 - 1891
• Main Authors: Audemar, Maïté, Ciotonea, Carmen, De Oliveira Vigier, Karine, Royer, Sébastien, Ungureanu, Adrian, Dragoi, Brindusa, Dumitriu, Emil, Jérôme, François
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 08.06.2015; WILEY‐VCH Verlag; Wiley Subscription Services, Inc; ChemPubSoc Europe/Wiley
• Subjects: Alcohol; biomass; Catalysis; Catalysts; Catalytic converters; Chemical Sciences; cobalt; Cobalt - chemistry; Conversion; Furaldehyde - chemistry; Furans - chemistry; Furfural; Furfuryl alcohol; heterogeneous catalysis; Hydrogen - chemistry; Hydrogenation; Kinetics; Levulinic acid; Levulinic Acids - chemistry; Models, Molecular; Molecular Conformation; Nanoparticles - chemistry; Oxidation-Reduction; Porosity; Pressure; Selectivity; Silicon Dioxide - chemistry; Solvents; supported catalysts; Temperature; biomass; cobalt; heterogeneous catalysis; supported catalysts; hydrogenation
• ISSN: 1864-5631; 1864-564X
• DOI: 10.1002/cssc.201403398

The hydrogenation of furfural to furfuryl alcohol was performed in the presence of a Co/SBA‐15 catalyst. High selectivity (96 %) at a conversion higher than 95 % is reported over this catalytic system. As the conversion of furfural to furfuryl alcohol occurs over metallic Co sites, the effect of reduction temperature, H2 pressure, and reaction temperature were studied. Optimum reaction conditions were: 150 °C, 1.5 h, 2.0 MPa of H2. The catalyst was recyclable, and furfuryl alcohol was recovered with a purity higher than 90 %. The effect of the solvent concentration was also studied. With a minimum of 50 wt % of solvent, the selectivity to furfuryl alcohol and the conversion of furfural remained high (both over 80 %). Likewise, the activity of the catalyst is maintained even in pure furfural, which confirms the real potential of the proposed catalytic system. This catalyst was also used in the hydrogenation of levulinic acid to produce γ‐valerolactone selectively. The fast and the furfural: Furfuryl alcohol is produced from furfural with a yield of 88 % in the presence of a recyclable and stable Co/SBA‐15 catalyst at 150 °C under H2 pressure in ethanol. This catalyst is also active and selective in the hydrogenation of levulinic acid to γ‐valerolactone.