Crystal Structure of (5,14-Methyl-7,12-dimethyl-1,4,8,11-tetraazadiimine-cyclotetradecylene-N,N',N'',N''')nickel(II) Bis(diisopropyldithiophosphate) Complex

The macrocyclic tetradentate Ni(II) compound was obtained in a reaction and determined by X-ray diffraction. The crystal structure shows that the molecule is centrosymmetric, and Ni atom located in a square planar coordination environment. The two [(iPrO)2PS2]- anions are outside the macrocycle comp...

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Bibliographic Details
Published inAnalytical Sciences Vol. 19; no. 4; pp. 643 - 644
Main Authors JIAN, Fangfang, JIAO, Kui, LIU, Faqian, WANG, Qingxiang
Format Journal Article
LanguageEnglish
Published Tokyo The Japan Society for Analytical Chemistry 01.04.2003
Japan Society for Analytical Chemistry
Japan Science and Technology Agency
Subjects
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Metal complexes
Physics
Single-crystal and powder diffraction
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
X-ray diffraction and scattering
Cationic complex
Transition elements Complexes
Nickel Complexes
Molecular structure
Nitrogen heterocycle
Complexes Mixed
Organic ligand
XRD
Tetradentate ligand
Experimental study
Organic dithiophosphate
Crystal structure
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Summary:The macrocyclic tetradentate Ni(II) compound was obtained in a reaction and determined by X-ray diffraction. The crystal structure shows that the molecule is centrosymmetric, and Ni atom located in a square planar coordination environment. The two [(iPrO)2PS2]- anions are outside the macrocycle complex to balance. The Ni-N bond lengths are in the range of 1.906(2) to 1.950(2)Å.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0910-6340
1348-2246
DOI:10.2116/analsci.19.643