Crystal Structure of (5,14-Methyl-7,12-dimethyl-1,4,8,11-tetraazadiimine-cyclotetradecylene-N,N',N'',N''')nickel(II) Bis(diisopropyldithiophosphate) Complex
The macrocyclic tetradentate Ni(II) compound was obtained in a reaction and determined by X-ray diffraction. The crystal structure shows that the molecule is centrosymmetric, and Ni atom located in a square planar coordination environment. The two [(iPrO)2PS2]- anions are outside the macrocycle comp...
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Published in | Analytical Sciences Vol. 19; no. 4; pp. 643 - 644 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Tokyo
The Japan Society for Analytical Chemistry
01.04.2003
Japan Society for Analytical Chemistry Japan Science and Technology Agency |
Subjects | |
Online Access | Get full text |
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Summary: | The macrocyclic tetradentate Ni(II) compound was obtained in a reaction and determined by X-ray diffraction. The crystal structure shows that the molecule is centrosymmetric, and Ni atom located in a square planar coordination environment. The two [(iPrO)2PS2]- anions are outside the macrocycle complex to balance. The Ni-N bond lengths are in the range of 1.906(2) to 1.950(2)Å. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0910-6340 1348-2246 |
DOI: | 10.2116/analsci.19.643 |