Balancing activity, stability and conductivity of nanoporous core-shell iridium/iridium oxide oxygen evolution catalysts

• Published in: Nature communications Vol. 8; no. 1; pp. 1449 - 8
• Main Authors: Kim, Yong-Tae, Lopes, Pietro Papa, Park, Shin-Ae, Lee, A-Yeong, Lim, Jinkyu, Lee, Hyunjoo, Back, Seoin, Jung, Yousung, Danilovic, Nemanja, Stamenkovic, Vojislav, Erlebacher, Jonah, Snyder, Joshua, Markovic, Nenad M.
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 13.11.2017; Nature Publishing Group; Nature Portfolio
• Subjects: 639/301/299/886; 639/301/357/537; Alloys; Catalysis; Catalysts; Conductivity; Etching; Evolution; Humanities and Social Sciences; Hydrogen; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Iridium; Materials selection; Morphology; multidisciplinary; Nanoparticles; Osmium; Oxygen; Oxygen evolution reactions; Science; Science (multidisciplinary); Shell stability; Thin films
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-017-01734-7

The selection of oxide materials for catalyzing the oxygen evolution reaction in acid-based electrolyzers must be guided by the proper balance between activity, stability and conductivity—a challenging mission of great importance for delivering affordable and environmentally friendly hydrogen. Here we report that the highly conductive nanoporous architecture of an iridium oxide shell on a metallic iridium core, formed through the fast dealloying of osmium from an Ir 25 Os 75 alloy, exhibits an exceptional balance between oxygen evolution activity and stability as quantified by the activity-stability factor. On the basis of this metric, the nanoporous Ir/IrO 2 morphology of dealloyed Ir 25 Os 75 shows a factor of ~30 improvement in activity-stability factor relative to conventional iridium-based oxide materials, and an ~8 times improvement over dealloyed Ir 25 Os 75 nanoparticles due to optimized stability and conductivity, respectively. We propose that the activity-stability factor is a key “metric” for determining the technological relevance of oxide-based anodic water electrolyzer catalysts. Production of affordable, clean hydrogen relies on efficient oxygen evolution, but improving catalytic performance for the reaction in acidic media is challenging. Here the authors show how tuning the nanoporous morphology of iridium/iridium oxide leads to an improvement in activity/stability, compared with conventional iridium-based oxides.