Facile synthesis of MOF-derived N doped ZnO/C nanoparticles and its adsorption activity toward dye removal

• Published in: BMC chemistry Vol. 17; no. 1; p. 126
• Main Authors: Abas, Khadiga Mohamed, Al Kiey, Sherief A.
• Format: Journal Article
• Language: English
• Published: Cham Springer International Publishing 26.09.2023; BioMed Central Ltd; Springer Nature B.V; BMC
• Subjects: Adsorption; Analysis; Carbon; Carbonization; Chemistry; Chemistry and Materials Science; Chemistry/Food Science; Dyes; Metal-organic frameworks; MOFs; Nanoparticles; Nitrogen; Porosity; Purification; Pyrolysis; Room temperature; Sewage; Surface area; Surface chemistry; Thermodynamics; Wastewater; Wastewater treatment; X ray photoelectron spectroscopy; ZIF-8; Zinc chloride; Zinc oxide; Carbonization; MOFs; ZIF-8; Adsorption
• ISSN: 2661-801X; 2661-801X
• DOI: 10.1186/s13065-023-01038-6

Metal–organic framework (MOF)-derived materials have gained an increasing interest and showed potential adsorption features in numerous applications. Significant attempts have been performed to boost the structure, functionality, surface area and porosity in addition to adsorption performance of MOF-derived carbon nanoparticles. Here, nitrogen-doped ZnO/carbon nanoparticles were synthesized by directly pyrolysis of Zn based metal organic framework (ZIF-8) in a nitrogen atmosphere at two different temperatures (600 and 800 °C), followed by chemical impregnation with ZnCl 2 solution with ratio (10:1) wt/wt , and thermal activation at 500 °C for 1 h. SEM, TEM, XPS, nitrogen adsorption–desorption method, and TGA characterization techniques were employed to investigate the morphology and structure characteristics. Then, thorough analysis of N doped ZnO/C-(600 and 800), adsorption capacity to remove Remazol brilliant blue reactive (RBBR) dye from aqueous phase was conducted. At room temperature, the porous N doped ZnO/C with high surface area attained a maximum adsorption capacity about 49.3 mg/g and demonstrated a strong adsorption capacity toward RBBR dye. The insights of kinetic, thermodynamic and adsorption isotherm studies of the as-demonstrated samples open up more discussion for MOFs-derived carbon adsorbents for wastewater treatment.