Structural, thermal, and gas transport properties of HDPE/LLDPE blend-based nanocomposites using a mixture of HDPE-g-MA and LLDPE-g-MA as compatibilizer

• Published in: Polymer engineering and science Vol. 56; no. 7; pp. 765 - 775
• Main Authors: Roberto Passador, Fabio, Collà Ruvolo-Filho, Adhemar, Pessan, Luiz Antonio
• Format: Journal Article
• Language: English
• Published: Newtown Blackwell Publishing Ltd 01.07.2016; Society of Plastics Engineers, Inc
• Subjects: Carbon dioxide; Clay; Compatibility; High density; Maleic anhydride; Montmorillonite; Morphology; Nanocomposites; Nanostructure; Permeability; Polyethylene; Polyethylenes; Polymers; Thermal properties
• ISSN: 0032-3888; 1548-2634
• DOI: 10.1002/pen.24305

Nanocomposites based on high density polyethylene (HDPE)/linear low density polyethylene (LLDPE) blend were prepared by melt compounding in a twin‐screw extruder using organoclay (montmorillonite) as nano‐filler and a 50/50 wt% mixture of maleic anhydride functionalized high density polyethylene (HDPE‐g‐MA) and linear low density polyethylene (LLDPE‐g‐MA) as the compatibilizing system. The addition of a maleated polyethylene‐based compatibilizing system was required to improve the organoclay dispersion in the HDPE/LLDPE blend‐based nanocomposite. In this work, the relationships between thermal properties, gas transport properties, and morphology were correlated. The compatibilized nanocomposite exhibited an intercalated morphology with a small number of individual platelets dispersed in the HDPE/LLDPE matrix, leading to an significant decrease in the oxygen permeation coefficient of the nanocomposites. A decrease in the carbon dioxide permeability and oxygen permeability with increase of nanoclay was observed for the compatibilized nanocomposites. The carbon dioxide permeability of the compatibilized nanocomposites was lower than the carbon dioxide permeability of the uncompatibilized nanocomposites even with the low intrinsic barrier properties of the compatibilizer. These effects were attributed to a good dispersion of the inorganic filler, good wettability of the filler by the polymer matrix, and strong interactions at the interface that increased the tortuous path for diffusion. Theoretical permeability models were used to estimate the final aspect ratio of nanoclay in the nanocomposite and showed good agreement with the aspect ratio obtained directly from TEM images. POLYM. ENG. SCI., 56:765–775, 2016. © 2016 Society of Plastics Engineers