Two-dimensional tessellation by molecular tiles constructed from halogen–halogen and halogen–metal networks

• Published in: Nature communications Vol. 9; no. 1; pp. 4871 - 8
• Main Authors: Cheng, Fang, Wu, Xue-Jun, Hu, Zhixin, Lu, Xuefeng, Ding, Zijing, Shao, Yan, Xu, Hai, Ji, Wei, Wu, Jishan, Loh, Kian Ping
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 19.11.2018; Nature Publishing Group; Nature Portfolio
• Subjects: 147/138; 639/638/298; 639/638/541/966; 639/638/542; Benzene; Chemistry; Construction; Crystal lattices; Crystals; Domains; Fabrication; Graphene; Humanities and Social Sciences; Hydrocarbons; Laboratories; multidisciplinary; Parallelograms; Phases; Photonic crystals; Physics; Polygons; Science; Science (multidisciplinary); Self-assembly; Self-similarity; Similarity; Symmetry; Tessellation; Tiles; Triangles
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-018-07323-6

Molecular tessellations are often discovered serendipitously, and the mechanisms by which specific molecules can be tiled seamlessly to form periodic tessellation remain unclear. Fabrication of molecular tessellation with higher symmetry compared with traditional Bravais lattices promises potential applications as photonic crystals. Here, we demonstrate that highly complex tessellation can be constructed on Au(111) from a single molecular building block, hexakis(4-iodophenyl)benzene (HPBI). HPBI gives rise to two self-assembly phases on Au(111) that possess the same geometric symmetry but different packing densities, on account of the presence of halogen-bonded and halogen–metal coordinated networks. Sub-domains of these phases with self-similarity serve as tiles in the periodic tessellations to express polygons consisting of parallelograms and two types of triangles. Our work highlights the important principle of constructing multiple phases with self-similarity from a single building block, which may constitute a new route to construct complex tessellations. Molecular tessellations of complex tilings are difficult to design and construct. Here, the authors show that molecular tessellations can be formed from a single building block that gives rise to two distinct supramolecular phases, whose self-similar subdomains serve as tiles in the periodic tessellations.