Biochar increased water holding capacity but accelerated organic carbon leaching from a sloping farmland soil in China

• Published in: Environmental science and pollution research international Vol. 23; no. 2; pp. 995 - 1006
• Main Authors: Liu, Chen, Wang, Honglan, Tang, Xiangyu, Guan, Zhuo, Reid, Brian J, Rajapaksha, Anushka Upamali, Ok, Yong Sik, Sun, Hui
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01.01.2016; Springer Nature B.V
• Subjects: Adsorption; Agricultural land; agricultural soils; Aquatic Pollution; arable soils; Atmospheric Protection/Air Quality Control/Air Pollution; biochar; Carbon; Carbon - chemistry; carbon sinks; Charcoal; China; Dissolved organic carbon; Earth and Environmental Science; Ecological Assessment and Remediation (CLEAR 2014) Conference: Environmental Pollution and Remediation; Ecotoxicology; Emission measurements; Entisols; Environment; Environmental Chemistry; Environmental Health; field experimentation; fluorescence; Groundwater; Hydraulic properties; Laboratories; Land pollution; Leaching; loam soils; Mercury; Mixed cropping; Moisture content; nitrogen; Organic matter; Organic soils; Particle size; plant available water; Pore size; Pore water; porosity; Porous materials; rain; Remediation; Retention; River catchments; Selected Papers from the 2nd Contaminated Land; Size distribution; Soil - chemistry; Soil amendment; Soil organic matter; Soil pollution; soil pore water; Soil properties; Soil remediation; Soil types; Soil water; soil water retention; Soils; Spectrum analysis; Subsoils; Waste Water Technology; water holding capacity; Water Management; Water Pollution Control; watersheds; China; Yangtze River; China, People's Rep., Changjiang R; Soil; DOC; Biochar; Pore size distribution; Water holding capacity; EEM fluorescence
• ISSN: 0944-1344; 1614-7499
• DOI: 10.1007/s11356-015-4885-9

A hydrologically contained field study, to assess biochar (produced from mixed crop straws) influence upon soil hydraulic properties and dissolved organic carbon (DOC) leaching, was conducted on a loamy soil (entisol). The soil, noted for its low plant-available water and low soil organic matter, is the most important arable soil type in the upper reaches of the Yangtze River catchment, China. Pore size distribution characterization (by N₂ adsorption, mercury intrusion, and water retention) showed that the biochar had a tri-modal pore size distribution. This included pores with diameters in the range of 0.1–10 μm that can retain plant-available water. Comparison of soil water retention curves between the control (0) and the biochar plots (16 t ha⁻¹ on dry weight basis) demonstrated biochar amendment to increase soil water holding capacity. However, significant increases in DOC concentration of soil pore water in both the plough layer and the undisturbed subsoil layer were observed in the biochar-amended plots. An increased loss of DOC relative to the control was observed upon rainfall events. Measurements of excitation-emission matrix (EEM) fluorescence indicated the DOC increment originated primarily from the organic carbon pool in the soil that became more soluble following biochar incorporation.