Reduction of Polarization Field Strength in Fully Strained c-Plane InGaN/(In)GaN Multiple Quantum Wells Grown by MOCVD

• Published in: Nanoscale research letters Vol. 11; no. 1; pp. 519 - 6
• Main Authors: Zhang, Feng, Ikeda, Masao, Zhang, Shu-Ming, Liu, Jian-Ping, Tian, Ai-Qin, Wen, Peng-Yan, Cheng, Yang, Yang, Hui
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.12.2016; Springer Nature B.V
• Subjects: Chemistry and Materials Science; EMN Meeting; Field strength; Gallium nitrides; Indium; Indium gallium nitrides; Materials Science; Mathematical analysis; Metalorganic chemical vapor deposition; Molecular Medicine; Multi Quantum Wells; Nano Express; Nanochemistry; Nanoscale Science and Technology; Nanostructure; Nanotechnology; Nanotechnology and Microengineering; Organic chemicals; Organic chemistry; Photoluminescence; Photons; Polarization; Quantum wells; Reduction; Sapphire; Strain relaxation; Substrates; Wavelengths; X-ray diffraction; Reciprocal space mapping; InGaN/(In)GaN multiple quantum wells; Strain relaxation; Photoluminescence; Polarization field
• ISSN: 1931-7573; 1556-276X
• DOI: 10.1186/s11671-016-1732-y

The polarization fields in c-plane InGaN/(In)GaN multiple quantum well (MQW) structures grown on sapphire substrate by metal-organic chemical vapor deposition are investigated in this paper. The indium composition in the quantum wells varies from 14.8 to 26.5% for different samples. The photoluminescence wavelengths are calculated theoretically by fully considering the related effects and compared with the measured wavelengths. It is found that when the indium content is lower than 17.3%, the measured wavelengths agree well with the theoretical values. However, when the indium content is higher than 17.3%, the measured ones are much shorter than the calculation results. This discrepancy is attributed to the reduced polarization field in the MQWs. For the MQWs with lower indium content, 100% theoretical polarization can be maintained, while, when the indium content is higher, the polarization field decreases significantly. The polarization field can be weakened down to 23% of the theoretical value when the indium content is 26.5%. Strain relaxation is excluded as the origin of the polarization reduction because there is no sign of lattice relaxation in the structures, judging by the X-ray diffraction reciprocal space mapping. The possible causes of the polarization reduction are discussed.