Reinforcement corrosion initiation and activation times in concrete structures exposed to severe marine environments

• Published in: Cement and concrete research Vol. 39; no. 11; pp. 1068 - 1076
• Main Authors: Melchers, R.E., Li, C.Q.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01.11.2009; Elsevier
• Subjects: Applied sciences; Building structure; Buildings. Public works; Cements; Chloride; Concrete structure; Concretes; Construction (buildings and works); Corrosion; Corrosion environments; Durability. Pathology. Repairing. Maintenance; Exact sciences and technology; Long-term performance; Marine environments; Offshore structures; Reinforcement; Reinforcing steels; Reinforcement; Long-term performance; Chloride; Corrosion; Performance evaluation; Marine environment; Failure analysis; Chlorides; Concrete construction; Activation; Long term
• ISSN: 0008-8846; 1873-3948
• DOI: 10.1016/j.cemconres.2009.07.003

The corrosion of steel reinforcement bars in reinforced concrete structures exposed to severe marine environments usually is attributed to the aggressive nature of chloride ions. In some cases in practice corrosion has been observed to commence already within a few years of exposure even with considerable concrete cover to the reinforcement and apparently high quality concretes. However, there are a number of other cases in practice for which corrosion initiation took much longer, even in cases with quite modest concrete cover and modest concrete quality. Many of these structures show satisfactory long-term structural performance, despite having high levels of localized chloride concentrations at the reinforcement. This disparity was noted already more than 50 years ago, but appears still not fully explained. This paper presents a systematic overview of cases reported in the engineering and corrosion literature and considers possible reasons for these differences. Consistent with observations by others, the data show that concretes made from blast furnace cements have better corrosion durability properties. The data also strongly suggest that concretes made with limestone or non-reactive dolomite aggregates or sufficiently high levels of other forms of calcium carbonates have favourable reinforcement corrosion properties. Both corrosion initiation and the onset of significant damage are delayed. Some possible reasons for this are explored briefly.