白炭黑/纳米甲壳素/多层石墨烯对溶聚丁苯橡胶/顺丁橡胶并用胶性能的影响

将白炭黑、纳米甲壳素与多层石墨烯三者并用填充溶聚丁苯橡胶（SSBR）/顺丁橡胶（BR）并用胶,考察了多层石墨烯用量对并用胶硫化特性、物理机械性能、耐老化性能及Payne效应的影响。结果表明,加入多层石墨烯后,SSBR/BR混炼胶的焦烧时间及正硫化时间明显缩短,硫化速率加快,加工性能得到改善;随着多层石墨烯用量的增加,SSBR/BR硫化胶的拉伸强度略提高后降低,100%定伸应力及300%定伸应力逐渐降低,扯断伸长率增大,撕裂强度及邵尔A硬度变化不大;经热空气老化后,SSBR/BR硫化胶的拉伸强度变化率明显降低,综合考虑,多层石墨烯最佳用量为1.0份;随着多层石墨烯用量的增加,SSBR/BR混炼胶...

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Bibliographic Details
Published in合成橡胶工业 Vol. 40; no. 6; pp. 462 - 466
Main Author 沈梅;张波;辛振祥
Format Journal Article
LanguageChinese
Published 青岛科技大学高分子科学与工程学院,山东青岛,266042 2017
Subjects
多层石墨烯
溶聚丁苯橡胶
物理机械性能
白炭黑
硫化特性
纳米甲壳素
耐老化性能
顺丁橡胶
nano chitin
多层石墨烯
aging resistance
silica
物理机械性能
白炭黑
curing characteristics
mechanical property
cis-1,4-polybutadiene rubber
溶聚丁苯橡胶
耐老化性能
multilayer graphene
硫化特性
纳米甲壳素
顺丁橡胶
solution-polymerized styrene-butadiene rubber
Online AccessGet full text
ISSN1000-1255
DOI10.3969/j.issn.1000-1255.2017.06.011

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Summary:将白炭黑、纳米甲壳素与多层石墨烯三者并用填充溶聚丁苯橡胶（SSBR）/顺丁橡胶（BR）并用胶,考察了多层石墨烯用量对并用胶硫化特性、物理机械性能、耐老化性能及Payne效应的影响。结果表明,加入多层石墨烯后,SSBR/BR混炼胶的焦烧时间及正硫化时间明显缩短,硫化速率加快,加工性能得到改善;随着多层石墨烯用量的增加,SSBR/BR硫化胶的拉伸强度略提高后降低,100%定伸应力及300%定伸应力逐渐降低,扯断伸长率增大,撕裂强度及邵尔A硬度变化不大;经热空气老化后,SSBR/BR硫化胶的拉伸强度变化率明显降低,综合考虑,多层石墨烯最佳用量为1.0份;随着多层石墨烯用量的增加,SSBR/BR混炼胶的Payne效应逐渐下降,而硫化胶的Payne效应变化不大。
Bibliography:nano chitin; silica; multilayer gra-phene; solution-polymerized styrene-butadiene rub-ber; cis-1,4-polybutadiene rubber; curing charac-teristics ; mechanical property; aging resistance
SHEN Mei, ZHANG Bo, XIN Zhen-xiang （School of Polymer Science and Engineering, Qingdao University of Science ＆ Technology, Qingdao 266042, China）
62-1036/TQ
Solution-polymerized styrene-butadiene rubber （ SSBR ）/cis-1, 4-butadiene rubber （ BR ） blends were filled with silica/nano ehitin/multilayer graphene, and the effects of amount of muhilayer gra- phene on curing characteristics, mechanical proper- ties, aging resistance and Payne effect of the blends were investigated. The results showed that the multi- layer graphene could shorten the scorch time and cu- ring time, accelerate the rate of vulcanization, and improve processability of SSBR/BR compounds. With increasing amount of muhilayer graphene, the tensile strength of the vulcanizates slightly increased first and then decreased, modulus at 100% and modulus at 300% decreased,
ISSN:1000-1255
DOI:10.3969/j.issn.1000-1255.2017.06.011